MPSuh's Energy and Environmental related Materials Lab. (백명현)






News
News: SELECTED AS INSIDE BACK COVER. "Copper-Organic Framework Fabricated with Nanosized CuS: Synthesis, Electrical Conductivity, and Electrocatalytic Activities for Oxygen Reduction Reaction"
Keumnam Cho, Sung-Hwan Han, and Myunghyun Paik Suh*,
Angew. Chem. Int. Ed. 2016, 55, 15301-15305
PDF
SELECTED AS A HOT PAPER. "Hydrogen Storage in a Potassium-Ion-Bound Metal–Organic Framework Incorporating Crown Ether Struts as Specific Cation Binding Sites"
Dr. Dae-Woon Lim, Seung An Chyun and Prof. Myunghyun Paik Suh*,
Angew. Chem. Int. Ed. 2014, 53, 7819-7822
PDF
FRONTISPIECE PAPER. "Enhancing CO2 Separation Ability of a Metal-Organic Framework by Post Synthetic Ligand Exchange with Flexible Aliphatic Carboxylates"
Dae Ho Hong, Myunghyun Paik Suh*,
Chem. Eur. J. 2014, 20, 426-434
PDF
BACKCOVER. "High CO2 Capture Ability of a Porous Organic Polymer Bi-functionalized with Carboxyl and Triazole Groups"
Lin-Hua Xie, Myunghyun Paik Suh*,
Chem. Eur. J. 2013, 19, 11590-11597, PDF,
SELECTED AS A HOT PAPER & INSIDE COVER PAGE."Magnesium Nanocrystals Embedded in a Metal-Organic Framework: Hybrid Hydrogen Storage with Synergistic Effect on Physi- and Chemisorption",
Hexagonal-disk-shaped magnesium nanocrystals (Mg NCs) are fabricated within a porous metal-organic framework (MOF, see picture). The Mg NCs@MOF stores hydrogen by both physi- and chemisorptions, exhibiting synergistic effects to increase the isosteric heat of H2 physisorption compared with that of pristine MOF, and decrease the H2 chemisorption/desorption temperatures by 200 K compared with those of bare Mg powder.
Dae-Woon Lim, Ji Woong Yoon, Keun Yong Ryu, and Myunghyun Paik Suh*,
Angew. Chem. Int. Ed. 2012, 51, 9814-9817
INVITED PAPER."Fabrication of metal nanoparticles in metal–organic frameworks",
Hoi Ri Moon, Dae-Woon Lim and Myunghyun Paik Suh*,
Chem. Soc. Rev. 2013, DOI: 10.1039/C2CS35320B
INVITED PAPER. "Hydrogen Storage in Metal-Organic Frameworks",
Myunghyun Paik Suh*, Hye Jeong Park, Thazhe Kootteri Prasad, Dae-Woon Lim,
Chem. Rev. 2012, 112, 782-835. PDF
SELECTED AS A HOT PAPER."Highly Selective CO2 Capture in Flexible 3D Coordination Polymer Networks",
Keeping limber: 3D coordination polymers incorporating flexible pillars (see picture, left) exhibit highly selective adsorption of CO2 over N2, H2, and CH4 (see picture, right), thermal stability up to 300 [deg]C, as well as air and water stability, and allow efficient CO2 capture, storage, and sensing.

Related News

Angewandte Chemie News: Opening the Door for CO2
    (linked to innovations report. original news is NA)

spectroscopyNOW: Smokestack scrubber (2009.9.1)

Hye-Sun Choi, Myunghyun Paik Suh*,
Angew. Chem. Int. Ed. 2009, 48, 6865-6869. PDF
SELECTED AS A HOT PAPER. Enhanced Hydrogen Storage by Palladium Nanoparticles Fabricated in a Redox-Active Metal-Organic Framework
Quick on the uptake: Palladium nanoparticles were fabricated simply by immersing {[Zn3(ntb)2(EtOH)2]·4EtOH}n (1) in an MeCN solution of Pd(NO3)2 at room temperature, without any extra reducing agent. 3 wt % PdNPs@[1]0.54+(NO3-)0.54 significantly increase H2 uptake capacities, both at 77 K and 1 bar and at 298 K and high pressures (see picture, red curve) compared to [Zn3(ntb)2]n (black). ntb=4,4,4-nitrilotrisbenzoate.
Young Eun Cheon, Myunghyun Paik Suh, Prof. *
Angew. Chem. Int. Ed. 2009, 48, 2899-2903. article